The four photographs were taken in April at their family home in Norfolk.
The princess, who turns one on Monday, is seen walking - with the aid of a baby walker filled with blocks - for the first time in one of the images.
Kensington Palace said the Duke and Duchess of Cambridge were "delighted" to share the new pictures of Charlotte.
The princess was last seen in public at her christening last July - the first time the Cambridges had been seen as a family of four.
The new photographs show Charlotte wearing a blue collared dress with matching tights and white cardigan, and a similar outfit in pink.
The duke, duchess, Charlotte and Prince George live at Anmer Hall, on the Queen's Sandringham Estate.
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